Construct · 1 fields · 1 citations

through-bond interaction: a standalone construct

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Organic chemistry

electronic coupling between distant orbitals relayed through the intervening sigma bonds rather than by direct overlap in space.

In organic chemistry, through-bond interaction refers to electronic coupling between distant orbitals relayed through the intervening sigma bonds rather than by direct overlap in space. This meaning comes from Hoffmann (1971) in Accounts of Chemical Research.[1]

Unit
Recovery means
Measured by

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Nearby constructs

accounts1 fields · 1 citationsanchor · a standalone construct coupling4 fields · 4 citationsjingle · one word, four constructs interaction3 fields · 7 citationsjingle · one word, three constructs

References

Hoffmann, R. (1971). Interaction of orbitals through space and through bonds. Accounts of Chemical Research, 4(1), 1-9. https://doi.org/10.1021/ar50037a001

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