Construct · 1 fields · 1 citations

Wigner tunneling correction: a standalone construct

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Chemical kinetics

a first-order quantum correction factor to transition state rate constants based on the imaginary barrier frequency and temperature.

In chemical kinetics, Wigner tunneling correction refers to a first-order quantum correction factor to transition state rate constants based on the imaginary barrier frequency and temperature. This meaning comes from Wigner (1932) in Zeitschrift für Physikalische Chemie.[1]

Unit
Recovery means
Measured by

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Nearby constructs

barrier4 fields · 7 citationsjingle · one word, four constructs factor3 fields · 4 citationsjingle · one word, three constructs frequency4 fields · 7 citationsjingle · one word, four constructs

References

Wigner, E. (1932). Über das Überschreiten von Potentialschwellen bei chemischen Reaktionen. Zeitschrift für Physikalische Chemie, 19B(1). https://doi.org/10.1515/zpch-1932-0120

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