Construct · 1 fields · 1 citations

exchange-enhanced reactivity: a standalone construct

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Bioinorganic chemistry

the lowering of bond activation barriers at metal-oxo species when the transition state gains extra exchange stabilization among unpaired d electrons.

In bioinorganic chemistry, exchange-enhanced reactivity refers to the lowering of bond activation barriers at metal-oxo species when the transition state gains extra exchange stabilization among unpaired d electrons. This meaning comes from Shaik (2010) in Nature Chemistry.[1]

Unit
Recovery means
Measured by

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Nearby constructs

activation4 fields · 4 citationsjingle · one word, four constructs bond2 fields · 2 citationsjingle · one word, two constructs exchange4 fields · 7 citationsjingle · one word, four constructs

References

Shaik, S., Chen, H., & Janardanan, D. (2010). Exchange-enhanced reactivity in bond activation by metal–oxo enzymes and synthetic reagents. Nature Chemistry, 3(1), 19-27. https://doi.org/10.1038/nchem.943

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