Construct · 1 fields · 1 citations

oxygen rebound mechanism: a standalone construct

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oxygen reboundmechanism1 CONSTRUCTOxygen rebound mechanismGROVES · BIOINORGANIC

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Bioinorganic chemistry

hydroxylation in which a high-valent iron-oxo species removes a hydrogen atom and the resulting carbon radical then recombines with the iron-bound hydroxyl.

In bioinorganic chemistry, oxygen rebound mechanism refers to hydroxylation in which a high-valent iron-oxo species removes a hydrogen atom and the resulting carbon radical then recombines with the iron-bound hydroxyl. This meaning comes from Groves (1976) in Journal of the American Chemical Society.[1]

Unit
Recovery means
Measured by

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Nearby constructs

mechanism4 fields · 4 citationsjingle · one word, four constructsradical3 fields · 5 citationsjingle · one word, three constructsrebound4 fields · 6 citationsjingle · one word, four constructs

References

  1. Groves, J. T., & McClusky, G. A. (1976). Aliphatic hydroxylation via oxygen rebound. Oxygen transfer catalyzed by iron. Journal of the American Chemical Society, 98(3), 859-861. https://doi.org/10.1021/ja00419a049

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