Construct · 1 fields · 1 citations

sigma-complex-assisted metathesis: a standalone construct

One name. One construct. A landmark on the map.

● anchor · a standalone construct Nearest construct by meaning·not indexed
sigma-complex-assistedmetathesis1 CONSTRUCTSigma-complex-assistedPERUTZ · ORGANOMETALLIC

A single standalone construct; nearby constructs are located against it in the Collider. Tap a field for its definition, unit, and measures.

Organometallic chemistry

a pathway at late transition metals in which bond exchange passes through sigma-complex intermediates without a change in metal oxidation state.

In organometallic chemistry, sigma-complex-assisted metathesis refers to a pathway at late transition metals in which bond exchange passes through sigma-complex intermediates without a change in metal oxidation state. This meaning comes from Perutz (2007) in Angewandte Chemie International Edition.[1]

Unit
Recovery means
Measured by

Next

Run it through the Collider, or take the citations with you.

See how sigma-complex-assisted metathesis sits against neighbouring constructs in the Collider, or export every reference on this page in one click.

Open in ColliderExport BibTeXReport this entry

Nearby constructs

bond2 fields · 2 citationsjingle · one word, two constructsexchange4 fields · 7 citationsjingle · one word, four constructsmetathesis2 fields · 2 citationsjingle · one word, two constructs

References

  1. Perutz, R. N., & Sabo‐Etienne, S. (2007). The σ‐CAM Mechanism: σ Complexes as the Basis of σ‐Bond Metathesis at Late‐Transition‐Metal Centers. Angewandte Chemie International Edition, 46(15), 2578-2592. https://doi.org/10.1002/anie.200603224

Cited on this page?

Confirm your construct, or correct us.

If your work is cited behind one of these entries, you know better than we do whether we captured the meaning right. Confirm it, suggest an edit, or dispute it, and your name goes on the entry as an author who has checked it, linked to your ORCID.

Claim your construct