Construct · 1 fields · 1 citations

stereochemically active lone pair: a standalone construct

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stereochemicallyactive lone pair1 CONSTRUCTStereochemically activeWALSH · MAIN-GROUP CHEMISTRY

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Main-group chemistry

an asymmetric electron density on heavy post-transition metal cations that distorts structures, explained as mixing of metal s and anion p states rather than plain s-p hybridization.

In main-group chemistry, stereochemically active lone pair refers to an asymmetric electron density on heavy post-transition metal cations that distorts structures, explained as mixing of metal s and anion p states rather than plain s-p hybridization. This meaning comes from Walsh (2011) in Chemical Society Reviews.[1]

Unit
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Nearby constructs

density4 fields · 6 citationsjingle · one word, four constructshybridization3 fields · 5 citationsjingle · one word, three constructsmixing3 fields · 5 citationsjingle · one word, three constructs

References

  1. Walsh, A., Payne, D. J., Egdell, R. G., & Watson, G. W. (2011). Stereochemistry of post-transition metal oxides: revision of the classical lone pair model. Chemical Society Reviews, 40(9), 4455. https://doi.org/10.1039/c1cs15098g

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