Construct · 1 fields · 1 citations

Tolman electronic parameter: a standalone construct

One name. One construct. A landmark on the map.

● anchor · a standalone construct Nearest construct by meaning·not indexed
Tolman electronicparameter1 CONSTRUCTTolman electronicTOLMAN · INORGANIC CHEMISTRY

A single standalone construct; nearby constructs are located against it in the Collider. Tap a field for its definition, unit, and measures.

Inorganic chemistry

a measure of a phosphine ligand's net electron donation, taken from the carbonyl stretching frequency of its nickel tricarbonyl complex.

In inorganic chemistry, Tolman electronic parameter refers to a measure of a phosphine ligand's net electron donation, taken from the carbonyl stretching frequency of its nickel tricarbonyl complex. This meaning comes from Tolman (1977) in Chemical Reviews.[1]

Unit
Recovery means
Measured by

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Nearby constructs

Tolman cone angle1 fields · 1 citationsanchor · a standalone constructcomplex4 fields · 4 citationsjingle · one word, four constructsfrequency4 fields · 7 citationsjingle · one word, four constructs

References

  1. Tolman, C. A. (1977). Steric effects of phosphorus ligands in organometallic chemistry and homogeneous catalysis. Chemical Reviews, 77(3), 313-348. https://doi.org/10.1021/cr60307a002

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