Construct · 3 fields · 4 citations
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Syneresis is the spontaneous shrinkage of a gel as its network of bonds continues to form and draw tighter after the gel has set, forcing out some of the liquid it once held. The phenomenon belongs to the colloid science founded in Graham's 1861 Liquid diffusion applied to analysis, which first distinguished colloidal gels, and Scherer's 1989 Mechanics of syneresis I. Theory gave its quantitative account, treating the shrinkage as the network's elastic contraction balanced against the drag of liquid flowing out through the pores. The referent is a contracting gel network expelling its pore fluid, measured by the volume of liquid released over time, the same process that cracks water-laid sediments and weeps whey from cheese curd.[1][2]
Sedimentologists invoke the same construct to explain certain cracks in ancient mudrocks that formed underwater rather than by drying in air: a freshly deposited clay gel contracts as its particles reorganise, and the subaqueous shrinkage opens discontinuous, often spindle-shaped cracks later filled by sediment. Plummer and Gostin's 1981 Shrinkage cracks: Desiccation or synaeresis? weighed this interpretation against drying and set criteria for telling the two apart. It is the identical gel-contraction construct as in the chemist's beaker, read from the rock record and diagnosed by crack shape, filling, and the absence of exposure features rather than by a measured volume of expelled water.[3]
In dairy science syneresis is the central step of cheesemaking and a defect in set yoghurt: once rennet or acid sets the milk into a gel, the casein network contracts and expels whey, and controlling how fast and how far it does so sets the moisture, and therefore the identity, of the finished cheese. Lodaite and colleagues' 2000 One-dimensional syneresis of rennet-induced gels measured this contraction directly in milk gels. It is the same gel-contraction-expelling-liquid construct as in colloid science and in cracking sediments, here harnessed to drive water out of curd and measured by the rate and extent of whey release.[4]
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